Football development show people all over the world are immersed in football matches, no matter men, women or kids are fond of football games. People are filled with passion in World Cup 2010 show the popularity of football. For men, they may just appreciate excellent football match, with skills and strategy. But women, rare of them know the rule of football match, what attractive them maybe football stars and their football shoes....more
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Bromido(3,5-dimethylpyrazole-N)[hydrotris(3,5-dimethylpyrazolyl)borato-3N,N',N'']copper(II)X.-J. Zhang, J. Han, C.-G. Wang and Y.-H. XingAbstract: In the title copper complex, [CuBr(C15H22BN6)(C5H8N2)], the CuII atom is coordinated by one Br atom, three N atoms from the hydrotris(3,5-dimethylpyrazolyl)borate ligand and one N atom from the 3,5-dimethylpyrazole ligand, forming a distorted trigonal-bipyramidal geometry. The equatorial positions are occupied by the Br atom and the N atoms of the hydrotris(3,5-dimethylpyrazolyl)borate ligand4-(3,5-Dimethyl-1H-pyrazol-4-ylmethyl)-3,5-dimethyl-1H-pyrazol-2-ium dihydrogen phosphate: a combined X-ray and DFT studyD. K. Hazra, R. Chatterjee, M. Ali and M. MukherjeeAbstract: The molecular structure of the title salt, C11H17N4+·H2PO4-, has been determined from single-crystal X-ray analysis and compared with the structure calculated by density functional theory (DFT) at the BLYP level. The crystal packing in the title compound is stabilized primarily by intermolecular N-HO, O-HN and O-HO hydrogen bonds and - stacking interactions, and thus a three-dimensional supramolecular honeycomb network consisting of R42(10),...more
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